Bistable N-H···N hydrogen bonds for reversibly modulating the dynamic motion in an organic co-crystal.

نویسندگان

  • Chengmin Ji
  • Shenhui Li
  • Feng Deng
  • Sijie Liu
  • Muhammad Adnan Asghar
  • Zhihua Sun
  • Maochun Hong
  • Junhua Luo
چکیده

Bistable N-H···N hydrogen bonds between rotors and stators enable delicate modulation of dynamic molecular motion by slowing down the fast rotation in a N-H···N hydrogen-bonded organic co-crystal of 1,2-diazabicyclo(2.2.2)octane bis(thiourea), which has been elucidated by the combination of variable-temperature (VT) X-ray structure analyses and VT solid-state nuclear magnetic resonance techniques.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 18 16  شماره 

صفحات  -

تاریخ انتشار 2016